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Circular microdisk mechanical resonators vibrating in their various resonance modes have emerged as important platforms for a wide spectrum of technologies including photonics, cavity optomechanics, optical metrology, and quantum optics. Optically transduced microdisk resonators made of advanced materials such as silicon carbide (SiC), diamond, and other wide- or ultrawide-bandgap materials are especially attractive. They are also of strong interest in the exploration of transducers or detectors for harsh environments and mission-oriented applications. Here we report on the first experimental investigation and analysis of energetic proton radiation effects on microdisk resonators made of 3C-SiC thin film grown on silicon substrate. We fabricate and study microdisks with diameters of ∼48 µm and ∼36 µm, and with multimode resonances in the ∼1 to 20 MHz range. We observe consistent downshifts of multimode resonance frequencies, and measure fractional frequency downshifts from the first three flexural resonance modes, up to ∼-3420 and -1660 ppm for two devices, respectively, in response to 1.8 MeV proton radiation at a dosage of 10¹⁴/cm². Such frequency changes are attributed to the radiation-induced Young’s modulus change of ∼0.38% and ∼0.09%, respectively. These devices also exhibit proton detection responsivity of ℜ ≈ -5 to -6 × 10⁻⁶Hz/proton. The results provide new knowledge of proton radiation effects in SiC materials, and may lead to better understanding and exploitation of micro/nanoscale devices for harsh-environment sensing, optomechanics, and integrated photonics applications.

 

Both electronic and ionic conductivities are of high importance to the performance of anode materials for Li-ion batteries. Many large capacity anode materials (such as Ge) do not have sufficiently high electronic and ionic conductivities required for high-rate cycling. Here, we report a novel ternary compound, copper germanium phosphide (CuGe 2 P 3 ), as a high-rate anode. Being synthesized via a facile and scalable mechanochemistry method, CuGe 2 P 3 has a cation-disordered sphalerite structure and offers higher ionic and electronic conductivities and better tolerance to volume change during cycling than Ge, as confirmed by first principles calculations and experimental characterization, including high-resolution synchrotron X-ray diffraction, HRTEM, SAED, XPS and Raman spectroscopy. Furthermore, the results suggest that CuGe 2 P 3 has a reversible Li-storage mechanism of conversion reaction. When composited with graphite by virtue of a two-stage ball-milling process, the yolk–shell structure of the amorphous carbon-coated CuGe 2 P 3 nanocomposite (CuGe 2 P 3 /C@Graphene) delivers a high initial coulombic efficiency (91%), a superior cycling stability (1312 mA h g −1 capacity after 600 cycles at 0.2 A g −1 and 876 mA h g −1 capacity after 1600 cycles at 2 A g −1 ), and an excellent rate capability (386 mA h g −1 capacity at 30 A g −1 ), surpassing most Ge-based anodes reported to date. Moreover, a series of cation-disordered new phases in the Cu(Zn)–Ge–P family with various cation ratios offer similar Li-storage properties, achieving high reversible capacities with high initial coulombic efficiencies and desirable redox chemistry with improved safety. 

The commercialization of high‐energy Li‐metal batteries is impeded by Li dendrites formed during electrochemical cycling and the safety hazards it causes. Here, a novel porous copper current collector that can effectively mitigate the dendritic growth of Li is reported. This porous Cu foil is fabricated via a simple two‐step electrochemical process, where Cu‐Zn alloy is electrodeposited on commercial copper foil and then Zn is electrochemically dissolved to form a 3D porous structure of Cu. The 3D porous Cu layers on average have a thickness of ≈14 um and porosity of ≈72%. This current collector can effectively suppress Li dendrites in cells cycled with a high areal capacity of 10 mAh cm⁻²and under a high current density of 10 mA cm⁻². This electrochemical fabrication method is facile and scalable for mass production. Results of advanced in situ synchrotron X‐ray diffraction reveal the phase evolution of the electrochemical deposition and dealloying processes.